Rare earth minerals including pyrochlore contain uranium, thorium and rare earths, and the processing of these rare earth ores must result in a mixed solution containing uranium, thorium and rare earths.
Many studies have been carried out to determine the concentration of individual components in the mixtures of uranium, thorium and rare earth, and thus, various instrumental methods have been widely used. However, these methods have disadvantages such as the need for special analytical tools, the need for sample solidification and the high cost of analysers concerned.
Due to the similar spectroscopic properties of uranium, thorium and rare earths, some analytical methods have been developed to separate uranium, thorium and rare earths and determine the concentration of individual components using various separation methods including extraction and ion exchange. However, these methods have other disadvantages such as long analysis time and complicated operation.
Kwon Myong Gang, a researcher at the Institute of Analysis, has investigated analytical methods for simultaneously determining individual components in a mixture of uranium, thorium and cerium obtained during the pyrochlore hydrometallurgical process, using spectrophotometric methods.
First, he proved that the maximum absorption wavelengths of uranium, thorium and cerium in three different solutions (3, 0.1mol/L HCl, 1mol/L CH3COOH) were 660, 652 and 660nm, respectively. Then, he used the relationship between the concentration of individual components and the absorbance to determine the absorption coefficients of individual components in different solutions. After that, based on the principle of absorbance additivity, he established a simulation equation between absorbance and concentration and used it to determine the concentration of individual components in the mixture solution. The concentration limit within which the additivity of absorbance in the mixed solution is established was less than 2mg/L of uranium and cerium, and 1.5mg/L of thorium. The error of analysis was less than 3%.
For further details, you can refer to his paper “Simultaneous Spectrophotometric Analysis of Uranium, Thorium, Cerium During Pyrochlore Hydrometallurgical Process” in “Proceedings of KUTIC-2025”.
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