Now cyanidation is the main method for producing gold from gold ore/concentrate.
It is well-known that gold in ore/concentrate is dissolved in the form of gold-cyanide complex by the action of cyanide and oxygen. During cyanidation, copper in the ore/concentrate readily reacts with cyanide to form stable cyanide complexes and under ordinary cyanidation conditions Cu(CN)32- is the dominant species in leach solution. Thus, the recovery of copper as well as cyanide from gold-plant wastewater will offer economic benefit.
AVR (acidification-volatilization-regeneration) technology, SART (sulfidization-acidification-recycling-thickening) process, electrowinning, membrane technologies, etc. have been developed to recover cyanide and/or copper, but each of these technologies has advantages and limitations and there is no universal method. Among these, AVR process has been used in industry owing to its simple principle and high effectiveness and robustness.
Kim Yong Il, a researcher at the Faculty of Metallic Engineering, evaluated sulfuric acid baking-leaching process to recover copper from precipitate containing Cu of 44.53 wt %, Fe of 5.56 wt % and S of 16.81 wt %, which comes from cyanidation wastewater treatment process by AVR (acidification-volatilization-regeneration) technology in a gold plant.
The experimental results showed that by acid baking under following conditions of 250℃, 60 min and the ratio of H2SO4 to copper precipitate 2.4:1, ~98.5 wt % copper was released to the leach solution, and that the leachate containing Cu and Fe can be sent to the conventional SX-EW process to produce electrolytic copper.
You can find the details in his paper “Acid Baking-Leaching Process for Treatment of Copper Precipitate from AVR Process” in “Russian Journal of Non-Ferrous Metals” (SCI).
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