As environmental protection is becoming more and more serious, it is a pressing task to reduce industrial waste as well as to develop eco-friendly material that can be used for people’s living.
Ri Chol Jin, a section head at the Faculty of Earth Science and Technology, has investigated a synthesis method of 13X zeolite using fine granite dust (FGD) resulting from granite processing. Zeolite has good physio-chemical properties as an adsorbent, a cation exchanger, a molecular sieve and a catalyst and it is widely used as a selective scavenger of heavy metals from liquid effluents.
He selected and applied both the alkaline fusion method (770-830℃, 80min) and the hydrothermal process (95-100℃, 8-12h) to the synthesis of 13X zeolite.
What is important in the synthesis of zeolite by using alkaline fusion method is high sintering temperature. He lowered the sintering temperature from 1 300℃ to 800℃ by putting FGD into water and maintaining it for 5 minutes to remove crystalline quartz which has low reactivity.
In addition, it is important to find appropriate sintering temperature at which albite is decomposed more easily than kalifeldspar in FGD because 13X zeolite is chemically concerned with sodium (Na). For this, he calculated the reaction heats of kalifeldspar and albite at the temperature range of 770~830℃.
As a result, he proved that albite has the possibility to be dissolved thermodynamically more easily than kalifeldspar, but the difference between the heat effects of albite and kalifeldspar is not so significant according to the increase in temperature.
Eventually, he successfully synthesized 13X zeolite from FGD with low energy consumption and all other stone processing waste can be recycled by this method.
For more information, you can refer to his paper “Characteristics of flourite{111} surface with various terminations: A first-principles investigation” in “Results in Surfaces and Interfaces” (SCOPUS).
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