The exhaustion of fossil fuel resources and constant evil effect of the global warming due to greenhouse gas emission needs the introduction of new kinds of energy system. Now, hydrogen energy system is attracting a great deal of attention as a reasonable energy system that can solve almost all kinds of environmental problems.
Proton exchange membrane (PEM) water electrolysis is considered as a main option to integrate and to miniaturize hydrogen energy systems. An advantage of PEM water electrolysis is short start-up time, high current density, high pressurized hydrogen production possibility and no use of corrosive solutions like alkali.
The kinds and properties of an anodic porous transport layer (PTL) play an important role in water management and ohmic resistance reduction. Some materials such as porous carbon materials (carbon fiber or carbon paper) and metals (Ti or Ni) can be used as the PTLs of PEM water electrolyzers.
Jang Tae Il, a researcher at the Institute of Nano Science and Technology, has concluded that the hot-pressed carbon paper is a superior PTL for improving the conductivity of the catalyst coated layer (CCL), and intensified his research to use carbon paper as an anodic PTL.
First, he found that anti-oxidized and hydrophilically treated carbon paper could be used as anodic PTL. Then, during the formation of a micro protective layer (MPL) by protective agents, he conducted plasma treatment of the hydrophobized carbon paper followed by impregnation with the hydrophilic polymer Nafion solution before repeating immersion-drying processes several times and heat treatment at 140℃ for 30 min to use carbon paper as anodic PTL.
PEM water electrolyzer prepared with the hydrophilic anodic PTL displayed desirable performance; initial voltage at 1.2A·cm-2 of current density at 80℃ was 1.76±0.02V, and finally measured voltage 1.84±0.02V after 6 270h of testing.
For more information, please refer to his paper “Hydrophilic treatment of carbon paper for anodic porous transport layer in proton exchange membrane water electrolyzer” in “Reaction Kinetics, Mechanisms and Catalysis” (SCI).
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